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Radiation luminescence of polymers—Emission behavior of aromatic compounds incorporated in synthetic rubbers

Identifieur interne : 007133 ( Main/Exploration ); précédent : 007132; suivant : 007134

Radiation luminescence of polymers—Emission behavior of aromatic compounds incorporated in synthetic rubbers

Auteurs : Shunichi Kawanishi [Japon] ; Miyuki Hagiwara [Japon]

Source :

Abstract

For a deep understanding of a radiation protection mechanism of some aromatic compounds on synthetic polymers, their optical emission behavior under electron irradiation was studied. The fluorescence light was led out of an irradiation room through a wave guide and detected by a photomultiplier so that less noisy spectrum was obtained. Acenaphthene or acenaphthylene was added to the synthetic rubbers such as ethylene propylene diene terpolymer, styrene butadiene rubber and cis-1,4-polybutadiene. The intensities of optical emission induced by electron beams changed from polymer to polymer, while those by ultraviolet lights were independent of the kind of polymers. The dependence of emission intensity on polymers under electron irradiation was estimated to show the fact that the radiation excited energy transfers occur from the polymer matrix to the additives and that an efficiency of the energy transfer is dependent on kinds of polymers.


Url:
DOI: 10.1016/1359-0197(86)90012-3


Affiliations:


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