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Radiation effects on crystalline polymers—I. Gamma-radiation-induced crosslinking and structural characterization of polyethylene oxide

Identifieur interne : 006276 ( Main/Exploration ); précédent : 006275; suivant : 006277

Radiation effects on crystalline polymers—I. Gamma-radiation-induced crosslinking and structural characterization of polyethylene oxide

Auteurs : Lihua Zhang [République populaire de Chine] ; Wende Zhang [République populaire de Chine] ; Zicheng Zhang [République populaire de Chine] ; Li Yu [République populaire de Chine] ; Hongfang Zhang [République populaire de Chine] ; Yuchen Qi [République populaire de Chine] ; Donglin Chen [République populaire de Chine]

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Abstract

By using WAXD, DSC and gel fraction determination techniques, the mechanism of radiation crosslinking of polyethylene oxide (PEO) was explored, and the dependence of aggregated state on the chemical reaction and physical structure was also discussed. It was found that just like other semi-crystalline polymers, the state of aggregation of the specimen has a profound influence on the radiation effects on PEO. On the contrary, the crystalline structure of the specimen is severely affected with the increase in radiation dose and eventually amorphortized when subjected to an extremely high radiation dose.


Url:
DOI: 10.1016/1359-0197(92)90215-2


Affiliations:


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