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Correlation between Composition, Structure and Properties of Poly(lactic acid)/Polyadipate‐Based Nano‐Biocomposites

Identifieur interne : 001180 ( Main/Exploration ); précédent : 001179; suivant : 001181

Correlation between Composition, Structure and Properties of Poly(lactic acid)/Polyadipate‐Based Nano‐Biocomposites

Auteurs : Ver Nica P. Martino [Espagne, France] ; Roxana A. Ruseckaite [Argentine] ; Alfonso Jiménez [Espagne] ; Luc Averous [France]

Source :

Mots-clés :

Abstract

Poly(lactic acid) plasticized with 15 and 20 wt.‐% of polyadipate was melt‐blended with different amounts of an O‐MMT (1–5 wt.‐%) to prepare nano‐biocomposites. The effect of plasticizer and nanofiller contents on the morphology and on thermal, mechanical and barrier properties of PLA‐based nano‐biocomposites was evaluated in order to understand their structure‐properties relationships. The oxygen transmission rate was notably reduced (around 45%) with increasing amount of clay due to an increased tortuosity. However, for clay concentrations above 3 wt.‐%, a significant detriment in ductile properties could also be observed. For a given amount of nanofiller, the increasing plasticizer concentration improved the clay dispersion through the polymeric matrix.


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DOI: 10.1002/mame.200900351


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