Serveur d'exploration sur la simulation d'un remplissage de moule

Attention, ce site est en cours de développement !
Attention, site généré par des moyens informatiques à partir de corpus bruts.
Les informations ne sont donc pas validées.

Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling

Identifieur interne : 005C38 ( Istex/Corpus ); précédent : 005C37; suivant : 005C39

Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling

Auteurs : Daniela Mileva ; Andrea Monami ; Dario Cavallo ; Giovanni C. Alfonso ; Giuseppe Portale ; René Androsch

Source :

Mots-clés :

Abstract

The crystallization behavior of a polyamide 6/organo‐modified montmorillonite (PA 6/OMMT) nanocomposite has been investigated by scanning chip calorimetry and wide‐angle X‐ray scattering, with emphasis placed on the evaluation of the effect of supercooling/cooling rate on the crystal/mesophase polymorphism of the PA 6 matrix. Presence of OMMT has negligible effect on the kinetics of formation of α‐crystals of PA 6 at low cooling rate while there is observed enhanced nucleation of γ‐mesophase on fast cooling. Furthermore, addition of OMMT leads to a distinct increase of the cooling rate required to completely vitrify the amorphous state. The performed experiments demonstrate that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at cooling conditions relevant in polymer processing.


Url:
DOI: 10.1002/mame.201200253

Links to Exploration step

ISTEX:2CAE4F3F6F214C2D912181892A3705445833746A

Le document en format XML

<record>
<TEI wicri:istexFullTextTei="biblStruct">
<teiHeader>
<fileDesc>
<titleStmt>
<title xml:lang="en">Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
<author>
<name sortKey="Mileva, Daniela" sort="Mileva, Daniela" uniqKey="Mileva D" first="Daniela" last="Mileva">Daniela Mileva</name>
<affiliation>
<mods:affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</mods:affiliation>
</affiliation>
<affiliation>
<mods:affiliation>Current address: Borealis Polyolefin GmbH, A‐4021 Linz, Austria</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Monami, Andrea" sort="Monami, Andrea" uniqKey="Monami A" first="Andrea" last="Monami">Andrea Monami</name>
<affiliation>
<mods:affiliation>Department of Engineering Sciences, University of Applied Sciences Merseburg, D‐06217 Merseburg, Germany</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Cavallo, Dario" sort="Cavallo, Dario" uniqKey="Cavallo D" first="Dario" last="Cavallo">Dario Cavallo</name>
<affiliation>
<mods:affiliation>Eindhoven University of Technology, Mechanical Engineering, Materials Technology, PO Box 513, GEM‐Z 4.22, 5600 MB Eindhoven, The Netherlands</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Alfonso, Giovanni C" sort="Alfonso, Giovanni C" uniqKey="Alfonso G" first="Giovanni C." last="Alfonso">Giovanni C. Alfonso</name>
<affiliation>
<mods:affiliation>Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, 16146 Genova, Italy</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Portale, Giuseppe" sort="Portale, Giuseppe" uniqKey="Portale G" first="Giuseppe" last="Portale">Giuseppe Portale</name>
<affiliation>
<mods:affiliation>ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), F‐38043 Grenoble, France</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Androsch, Rene" sort="Androsch, Rene" uniqKey="Androsch R" first="René" last="Androsch">René Androsch</name>
<affiliation>
<mods:affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</mods:affiliation>
</affiliation>
</author>
</titleStmt>
<publicationStmt>
<idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:2CAE4F3F6F214C2D912181892A3705445833746A</idno>
<date when="2013" year="2013">2013</date>
<idno type="doi">10.1002/mame.201200253</idno>
<idno type="url">https://api.istex.fr/document/2CAE4F3F6F214C2D912181892A3705445833746A/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">005C38</idno>
</publicationStmt>
<sourceDesc>
<biblStruct>
<analytic>
<title level="a" type="main" xml:lang="en">Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
<author>
<name sortKey="Mileva, Daniela" sort="Mileva, Daniela" uniqKey="Mileva D" first="Daniela" last="Mileva">Daniela Mileva</name>
<affiliation>
<mods:affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</mods:affiliation>
</affiliation>
<affiliation>
<mods:affiliation>Current address: Borealis Polyolefin GmbH, A‐4021 Linz, Austria</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Monami, Andrea" sort="Monami, Andrea" uniqKey="Monami A" first="Andrea" last="Monami">Andrea Monami</name>
<affiliation>
<mods:affiliation>Department of Engineering Sciences, University of Applied Sciences Merseburg, D‐06217 Merseburg, Germany</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Cavallo, Dario" sort="Cavallo, Dario" uniqKey="Cavallo D" first="Dario" last="Cavallo">Dario Cavallo</name>
<affiliation>
<mods:affiliation>Eindhoven University of Technology, Mechanical Engineering, Materials Technology, PO Box 513, GEM‐Z 4.22, 5600 MB Eindhoven, The Netherlands</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Alfonso, Giovanni C" sort="Alfonso, Giovanni C" uniqKey="Alfonso G" first="Giovanni C." last="Alfonso">Giovanni C. Alfonso</name>
<affiliation>
<mods:affiliation>Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, 16146 Genova, Italy</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Portale, Giuseppe" sort="Portale, Giuseppe" uniqKey="Portale G" first="Giuseppe" last="Portale">Giuseppe Portale</name>
<affiliation>
<mods:affiliation>ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), F‐38043 Grenoble, France</mods:affiliation>
</affiliation>
</author>
<author>
<name sortKey="Androsch, Rene" sort="Androsch, Rene" uniqKey="Androsch R" first="René" last="Androsch">René Androsch</name>
<affiliation>
<mods:affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</mods:affiliation>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series>
<title level="j">Macromolecular Materials and Engineering</title>
<title level="j" type="abbrev">Macromol. Mater. Eng.</title>
<idno type="ISSN">1438-7492</idno>
<idno type="eISSN">1439-2054</idno>
<imprint>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2013-09">2013-09</date>
<biblScope unit="volume">298</biblScope>
<biblScope unit="issue">9</biblScope>
<biblScope unit="page" from="938">938</biblScope>
<biblScope unit="page" to="943">943</biblScope>
</imprint>
<idno type="ISSN">1438-7492</idno>
</series>
<idno type="istex">2CAE4F3F6F214C2D912181892A3705445833746A</idno>
<idno type="DOI">10.1002/mame.201200253</idno>
<idno type="ArticleID">MAME201200253</idno>
</biblStruct>
</sourceDesc>
<seriesStmt>
<idno type="ISSN">1438-7492</idno>
</seriesStmt>
</fileDesc>
<profileDesc>
<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>cooling rate</term>
<term>crystallizations</term>
<term>nanocomposites</term>
<term>polyamide 6</term>
<term>polymorphism</term>
</keywords>
</textClass>
<langUsage>
<language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front>
<div type="abstract" xml:lang="en">The crystallization behavior of a polyamide 6/organo‐modified montmorillonite (PA 6/OMMT) nanocomposite has been investigated by scanning chip calorimetry and wide‐angle X‐ray scattering, with emphasis placed on the evaluation of the effect of supercooling/cooling rate on the crystal/mesophase polymorphism of the PA 6 matrix. Presence of OMMT has negligible effect on the kinetics of formation of α‐crystals of PA 6 at low cooling rate while there is observed enhanced nucleation of γ‐mesophase on fast cooling. Furthermore, addition of OMMT leads to a distinct increase of the cooling rate required to completely vitrify the amorphous state. The performed experiments demonstrate that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at cooling conditions relevant in polymer processing.</div>
</front>
</TEI>
<istex>
<corpusName>wiley</corpusName>
<author>
<json:item>
<name>Daniela Mileva</name>
<affiliations>
<json:string>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</json:string>
<json:string>Current address: Borealis Polyolefin GmbH, A‐4021 Linz, Austria</json:string>
</affiliations>
</json:item>
<json:item>
<name>Andrea Monami</name>
<affiliations>
<json:string>Department of Engineering Sciences, University of Applied Sciences Merseburg, D‐06217 Merseburg, Germany</json:string>
</affiliations>
</json:item>
<json:item>
<name>Dario Cavallo</name>
<affiliations>
<json:string>Eindhoven University of Technology, Mechanical Engineering, Materials Technology, PO Box 513, GEM‐Z 4.22, 5600 MB Eindhoven, The Netherlands</json:string>
</affiliations>
</json:item>
<json:item>
<name>Giovanni C. Alfonso</name>
<affiliations>
<json:string>Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, 16146 Genova, Italy</json:string>
</affiliations>
</json:item>
<json:item>
<name>Giuseppe Portale</name>
<affiliations>
<json:string>ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), F‐38043 Grenoble, France</json:string>
</affiliations>
</json:item>
<json:item>
<name>René Androsch</name>
<affiliations>
<json:string>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</json:string>
</affiliations>
</json:item>
</author>
<subject>
<json:item>
<lang>
<json:string>eng</json:string>
</lang>
<value>cooling rate</value>
</json:item>
<json:item>
<lang>
<json:string>eng</json:string>
</lang>
<value>crystallizations</value>
</json:item>
<json:item>
<lang>
<json:string>eng</json:string>
</lang>
<value>nanocomposites</value>
</json:item>
<json:item>
<lang>
<json:string>eng</json:string>
</lang>
<value>polyamide 6</value>
</json:item>
<json:item>
<lang>
<json:string>eng</json:string>
</lang>
<value>polymorphism</value>
</json:item>
</subject>
<articleId>
<json:string>MAME201200253</json:string>
</articleId>
<language>
<json:string>eng</json:string>
</language>
<originalGenre>
<json:string>article</json:string>
</originalGenre>
<abstract>The crystallization behavior of a polyamide 6/organo‐modified montmorillonite (PA 6/OMMT) nanocomposite has been investigated by scanning chip calorimetry and wide‐angle X‐ray scattering, with emphasis placed on the evaluation of the effect of supercooling/cooling rate on the crystal/mesophase polymorphism of the PA 6 matrix. Presence of OMMT has negligible effect on the kinetics of formation of α‐crystals of PA 6 at low cooling rate while there is observed enhanced nucleation of γ‐mesophase on fast cooling. Furthermore, addition of OMMT leads to a distinct increase of the cooling rate required to completely vitrify the amorphous state. The performed experiments demonstrate that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at cooling conditions relevant in polymer processing.</abstract>
<qualityIndicators>
<score>4.348</score>
<pdfVersion>1.3</pdfVersion>
<pdfPageSize>595.276 x 793.701 pts</pdfPageSize>
<refBibsNative>false</refBibsNative>
<keywordCount>5</keywordCount>
<abstractCharCount>827</abstractCharCount>
<pdfWordCount>2920</pdfWordCount>
<pdfCharCount>17994</pdfCharCount>
<pdfPageCount>6</pdfPageCount>
<abstractWordCount>119</abstractWordCount>
</qualityIndicators>
<title>Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
<genre>
<json:string>article</json:string>
</genre>
<host>
<volume>298</volume>
<publisherId>
<json:string>MAME</json:string>
</publisherId>
<pages>
<total>6</total>
<last>943</last>
<first>938</first>
</pages>
<issn>
<json:string>1438-7492</json:string>
</issn>
<issue>9</issue>
<subject>
<json:item>
<value>Communication</value>
</json:item>
</subject>
<genre>
<json:string>journal</json:string>
</genre>
<language>
<json:string>unknown</json:string>
</language>
<eissn>
<json:string>1439-2054</json:string>
</eissn>
<title>Macromolecular Materials and Engineering</title>
<doi>
<json:string>10.1002/(ISSN)1439-2054</json:string>
</doi>
</host>
<publicationDate>2013</publicationDate>
<copyrightDate>2013</copyrightDate>
<doi>
<json:string>10.1002/mame.201200253</json:string>
</doi>
<id>2CAE4F3F6F214C2D912181892A3705445833746A</id>
<score>0.18206555</score>
<fulltext>
<json:item>
<original>true</original>
<mimetype>application/pdf</mimetype>
<extension>pdf</extension>
<uri>https://api.istex.fr/document/2CAE4F3F6F214C2D912181892A3705445833746A/fulltext/pdf</uri>
</json:item>
<json:item>
<original>false</original>
<mimetype>application/zip</mimetype>
<extension>zip</extension>
<uri>https://api.istex.fr/document/2CAE4F3F6F214C2D912181892A3705445833746A/fulltext/zip</uri>
</json:item>
<json:item>
<original>false</original>
<mimetype>text/plain</mimetype>
<extension>txt</extension>
<uri>https://api.istex.fr/document/2CAE4F3F6F214C2D912181892A3705445833746A/fulltext/txt</uri>
</json:item>
<istex:fulltextTEI uri="https://api.istex.fr/document/2CAE4F3F6F214C2D912181892A3705445833746A/fulltext/tei">
<teiHeader>
<fileDesc>
<titleStmt>
<title level="a" type="main" xml:lang="en">Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
<respStmt>
<resp>Références bibliographiques récupérées via GROBID</resp>
<name resp="ISTEX-API">ISTEX-API (INIST-CNRS)</name>
</respStmt>
</titleStmt>
<publicationStmt>
<authority>ISTEX</authority>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<availability>
<p>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</p>
</availability>
<date>2013</date>
</publicationStmt>
<sourceDesc>
<biblStruct type="inbook">
<analytic>
<title level="a" type="main" xml:lang="en">Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
<author xml:id="author-1">
<persName>
<forename type="first">Daniela</forename>
<surname>Mileva</surname>
</persName>
<affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</affiliation>
<affiliation>Current address: Borealis Polyolefin GmbH, A‐4021 Linz, Austria</affiliation>
</author>
<author xml:id="author-2">
<persName>
<forename type="first">Andrea</forename>
<surname>Monami</surname>
</persName>
<affiliation>Department of Engineering Sciences, University of Applied Sciences Merseburg, D‐06217 Merseburg, Germany</affiliation>
</author>
<author xml:id="author-3">
<persName>
<forename type="first">Dario</forename>
<surname>Cavallo</surname>
</persName>
<affiliation>Eindhoven University of Technology, Mechanical Engineering, Materials Technology, PO Box 513, GEM‐Z 4.22, 5600 MB Eindhoven, The Netherlands</affiliation>
</author>
<author xml:id="author-4">
<persName>
<forename type="first">Giovanni C.</forename>
<surname>Alfonso</surname>
</persName>
<affiliation>Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, 16146 Genova, Italy</affiliation>
</author>
<author xml:id="author-5">
<persName>
<forename type="first">Giuseppe</forename>
<surname>Portale</surname>
</persName>
<affiliation>ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), F‐38043 Grenoble, France</affiliation>
</author>
<author xml:id="author-6">
<persName>
<forename type="first">René</forename>
<surname>Androsch</surname>
</persName>
<note type="correspondence">
<p>Correspondence: Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</p>
</note>
<affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</affiliation>
</author>
</analytic>
<monogr>
<title level="j">Macromolecular Materials and Engineering</title>
<title level="j" type="abbrev">Macromol. Mater. Eng.</title>
<idno type="pISSN">1438-7492</idno>
<idno type="eISSN">1439-2054</idno>
<idno type="DOI">10.1002/(ISSN)1439-2054</idno>
<imprint>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2013-09"></date>
<biblScope unit="volume">298</biblScope>
<biblScope unit="issue">9</biblScope>
<biblScope unit="page" from="938">938</biblScope>
<biblScope unit="page" to="943">943</biblScope>
</imprint>
</monogr>
<idno type="istex">2CAE4F3F6F214C2D912181892A3705445833746A</idno>
<idno type="DOI">10.1002/mame.201200253</idno>
<idno type="ArticleID">MAME201200253</idno>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc>
<creation>
<date>2013</date>
</creation>
<langUsage>
<language ident="en">en</language>
</langUsage>
<abstract xml:lang="en">
<p>The crystallization behavior of a polyamide 6/organo‐modified montmorillonite (PA 6/OMMT) nanocomposite has been investigated by scanning chip calorimetry and wide‐angle X‐ray scattering, with emphasis placed on the evaluation of the effect of supercooling/cooling rate on the crystal/mesophase polymorphism of the PA 6 matrix. Presence of OMMT has negligible effect on the kinetics of formation of α‐crystals of PA 6 at low cooling rate while there is observed enhanced nucleation of γ‐mesophase on fast cooling. Furthermore, addition of OMMT leads to a distinct increase of the cooling rate required to completely vitrify the amorphous state. The performed experiments demonstrate that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at cooling conditions relevant in polymer processing.</p>
</abstract>
<abstract xml:lang="en" style="graphical">
<p>It is demonstrated that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at rapid cooling conditions. Presence of OMMT has negligible effect on the kinetics of α‐crystal formation in PA 6, while enhanced nucleation of γ‐mesophase is observed. The cooling rate required to completely vitrify the amorphous state is increased.</p>
</abstract>
<textClass xml:lang="en">
<keywords scheme="keyword">
<list>
<head>keywords</head>
<item>
<term>cooling rate</term>
</item>
<item>
<term>crystallizations</term>
</item>
<item>
<term>nanocomposites</term>
</item>
<item>
<term>polyamide 6</term>
</item>
<item>
<term>polymorphism</term>
</item>
</list>
</keywords>
</textClass>
<textClass>
<keywords scheme="Journal Subject">
<list>
<head>article-category</head>
<item>
<term>Communication</term>
</item>
</list>
</keywords>
</textClass>
</profileDesc>
<revisionDesc>
<change when="2012-06-30">Received</change>
<change when="2013-09">Published</change>
<change xml:id="refBibs-istex" who="#ISTEX-API" when="2016-08-6">References added</change>
</revisionDesc>
</teiHeader>
</istex:fulltextTEI>
</fulltext>
<metadata>
<istex:metadataXml wicri:clean="Wiley component found">
<istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration>
<istex:document>
<component version="2.0" type="serialArticle" xml:lang="en">
<header>
<publicationMeta level="product">
<publisherInfo>
<publisherName>WILEY‐VCH Verlag</publisherName>
<publisherLoc>Weinheim</publisherLoc>
</publisherInfo>
<doi registered="yes">10.1002/(ISSN)1439-2054</doi>
<issn type="print">1438-7492</issn>
<issn type="electronic">1439-2054</issn>
<idGroup>
<id type="product" value="MAME"></id>
</idGroup>
<titleGroup>
<title type="main" xml:lang="en" sort="MACROMOLECULAR MATERIALS AND ENGINEERING">Macromolecular Materials and Engineering</title>
<title type="short">Macromol. Mater. Eng.</title>
</titleGroup>
<selfCitationGroup>
<citation type="ancestor" xml:id="cit1">
<journalTitle>Applied Macromolecular Chemistry and Physics</journalTitle>
<accessionId ref="info:x-wiley/issn/00033146">0003-3146</accessionId>
<pubYear year="1999">1999</pubYear>
<vol>273</vol>
<issue>1</issue>
</citation>
</selfCitationGroup>
</publicationMeta>
<publicationMeta level="part" position="90">
<doi origin="wiley" registered="yes">10.1002/mame.v298.9</doi>
<numberingGroup>
<numbering type="journalVolume" number="298">298</numbering>
<numbering type="journalIssue">9</numbering>
</numberingGroup>
<coverDate startDate="2013-09">September 2013</coverDate>
</publicationMeta>
<publicationMeta level="unit" type="article" position="4" status="forIssue">
<doi origin="wiley" registered="yes">10.1002/mame.201200253</doi>
<idGroup>
<id type="unit" value="MAME201200253"></id>
</idGroup>
<countGroup>
<count type="pageTotal" number="6"></count>
</countGroup>
<titleGroup>
<title type="articleCategory">Communication</title>
<title type="tocHeading1">Communication</title>
</titleGroup>
<copyright ownership="publisher">Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</copyright>
<eventGroup>
<event type="manuscriptReceived" date="2012-06-30"></event>
<event type="manuscriptRevised" date="2012-08-12"></event>
<event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:3.2.9 mode:FullText" date="2014-01-16"></event>
<event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.2.9 mode:FullText" date="2014-01-16"></event>
<event type="publishedOnlineEarlyUnpaginated" date="2012-12-06"></event>
<event type="publishedOnlineFinalForm" date="2013-09-03"></event>
<event type="firstOnline" date="2012-12-06"></event>
<event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.6.4 mode:FullText" date="2015-10-02"></event>
</eventGroup>
<numberingGroup>
<numbering type="pageFirst">938</numbering>
<numbering type="pageLast">943</numbering>
</numberingGroup>
<correspondenceTo>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</correspondenceTo>
<linkGroup>
<link type="toTypesetVersion" href="file:MAME.MAME201200253.pdf"></link>
</linkGroup>
</publicationMeta>
<contentMeta>
<countGroup>
<count type="figureTotal" number="4"></count>
<count type="tableTotal" number="0"></count>
<count type="referenceTotal" number="26"></count>
<count type="wordTotal" number="3211"></count>
</countGroup>
<titleGroup>
<title type="main" xml:lang="en">Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
<title type="short" xml:lang="en">Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
</titleGroup>
<creators>
<creator xml:id="au1" creatorRole="author" affiliationRef="#af1 #af2">
<personName>
<givenNames>Daniela</givenNames>
<familyName>Mileva</familyName>
</personName>
</creator>
<creator xml:id="au2" creatorRole="author" affiliationRef="#af3">
<personName>
<givenNames>Andrea</givenNames>
<familyName>Monami</familyName>
</personName>
</creator>
<creator xml:id="au3" creatorRole="author" affiliationRef="#af4">
<personName>
<givenNames>Dario</givenNames>
<familyName>Cavallo</familyName>
</personName>
</creator>
<creator xml:id="au4" creatorRole="author" affiliationRef="#af5">
<personName>
<givenNames>Giovanni C.</givenNames>
<familyName>Alfonso</familyName>
</personName>
</creator>
<creator xml:id="au5" creatorRole="author" affiliationRef="#af6">
<personName>
<givenNames>Giuseppe</givenNames>
<familyName>Portale</familyName>
</personName>
</creator>
<creator xml:id="au6" creatorRole="author" affiliationRef="#af1" corresponding="yes">
<personName>
<givenNames>René</givenNames>
<familyName>Androsch</familyName>
</personName>
<contactDetails>
<email normalForm="rene.androsch@iw.uni-halle.de">rene.androsch@iw.uni‐halle.de</email>
</contactDetails>
</creator>
</creators>
<affiliationGroup>
<affiliation xml:id="af1" countryCode="DE" type="organization">
<unparsedAffiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af2" countryCode="AT" type="organization">
<unparsedAffiliation>Current address: Borealis Polyolefin GmbH, A‐4021 Linz, Austria</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af3" countryCode="DE" type="organization">
<unparsedAffiliation>Department of Engineering Sciences, University of Applied Sciences Merseburg, D‐06217 Merseburg, Germany</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af4" countryCode="NL" type="organization">
<unparsedAffiliation>Eindhoven University of Technology, Mechanical Engineering, Materials Technology, PO Box 513, GEM‐Z 4.22, 5600 MB Eindhoven, The Netherlands</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af5" countryCode="IT" type="organization">
<unparsedAffiliation>Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, 16146 Genova, Italy</unparsedAffiliation>
</affiliation>
<affiliation xml:id="af6" countryCode="FR" type="organization">
<unparsedAffiliation>ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), F‐38043 Grenoble, France</unparsedAffiliation>
</affiliation>
</affiliationGroup>
<keywordGroup xml:lang="en" type="author">
<keyword xml:id="kwd1">cooling rate</keyword>
<keyword xml:id="kwd2">crystallizations</keyword>
<keyword xml:id="kwd3">nanocomposites</keyword>
<keyword xml:id="kwd4">polyamide 6</keyword>
<keyword xml:id="kwd5">polymorphism</keyword>
</keywordGroup>
<abstractGroup>
<abstract type="main" xml:lang="en">
<title type="main">Abstract</title>
<p>The crystallization behavior of a polyamide 6/organo‐modified montmorillonite (PA 6/OMMT) nanocomposite has been investigated by scanning chip calorimetry and wide‐angle X‐ray scattering, with emphasis placed on the evaluation of the effect of supercooling/cooling rate on the crystal/mesophase polymorphism of the PA 6 matrix. Presence of OMMT has negligible effect on the kinetics of formation of α‐crystals of PA 6 at low cooling rate while there is observed enhanced nucleation of γ‐mesophase on fast cooling. Furthermore, addition of OMMT leads to a distinct increase of the cooling rate required to completely vitrify the amorphous state. The performed experiments demonstrate that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at cooling conditions relevant in polymer processing.
<blockFixed type="graphic">
<mediaResourceGroup>
<mediaResource alt="image" eRights="yes" copyright="WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim" href="urn:x-wiley:14387492:media:MAME201200253:gra001"></mediaResource>
</mediaResourceGroup>
</blockFixed>
</p>
</abstract>
<abstract type="graphical" xml:lang="en">
<p>
<b>It is demonstrated that the nucleating effect</b>
of OMMT in PA 6/OMMT nanocomposites is of particular importance at rapid cooling conditions. Presence of OMMT has negligible effect on the kinetics of α‐crystal formation in PA 6, while enhanced nucleation of γ‐mesophase is observed. The cooling rate required to completely vitrify the amorphous state is increased.
<blockFixed type="graphic">
<mediaResourceGroup>
<mediaResource alt="image" eRights="yes" copyright="WILEY‐VCH Verlag" href="urn:x-wiley:14387492:media:MAME201200253:content"></mediaResource>
</mediaResourceGroup>
</blockFixed>
</p>
</abstract>
</abstractGroup>
</contentMeta>
</header>
</component>
</istex:document>
</istex:metadataXml>
<mods version="3.6">
<titleInfo lang="en">
<title>Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
</titleInfo>
<titleInfo type="abbreviated" lang="en">
<title>Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
</titleInfo>
<titleInfo type="alternative" contentType="CDATA" lang="en">
<title>Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling</title>
</titleInfo>
<name type="personal">
<namePart type="given">Daniela</namePart>
<namePart type="family">Mileva</namePart>
<affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</affiliation>
<affiliation>Current address: Borealis Polyolefin GmbH, A‐4021 Linz, Austria</affiliation>
<role>
<roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal">
<namePart type="given">Andrea</namePart>
<namePart type="family">Monami</namePart>
<affiliation>Department of Engineering Sciences, University of Applied Sciences Merseburg, D‐06217 Merseburg, Germany</affiliation>
<role>
<roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal">
<namePart type="given">Dario</namePart>
<namePart type="family">Cavallo</namePart>
<affiliation>Eindhoven University of Technology, Mechanical Engineering, Materials Technology, PO Box 513, GEM‐Z 4.22, 5600 MB Eindhoven, The Netherlands</affiliation>
<role>
<roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal">
<namePart type="given">Giovanni C.</namePart>
<namePart type="family">Alfonso</namePart>
<affiliation>Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, 16146 Genova, Italy</affiliation>
<role>
<roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal">
<namePart type="given">Giuseppe</namePart>
<namePart type="family">Portale</namePart>
<affiliation>ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), F‐38043 Grenoble, France</affiliation>
<role>
<roleTerm type="text">author</roleTerm>
</role>
</name>
<name type="personal">
<namePart type="given">René</namePart>
<namePart type="family">Androsch</namePart>
<affiliation>Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</affiliation>
<description>Correspondence: Center of Engineering Sciences, Martin‐Luther‐University Halle‐Wittenberg, D‐06099 Halle/Saale, Germany</description>
<role>
<roleTerm type="text">author</roleTerm>
</role>
</name>
<typeOfResource>text</typeOfResource>
<genre type="article" displayLabel="article"></genre>
<originInfo>
<publisher>WILEY‐VCH Verlag</publisher>
<place>
<placeTerm type="text">Weinheim</placeTerm>
</place>
<dateIssued encoding="w3cdtf">2013-09</dateIssued>
<dateCaptured encoding="w3cdtf">2012-06-30</dateCaptured>
<copyrightDate encoding="w3cdtf">2013</copyrightDate>
</originInfo>
<language>
<languageTerm type="code" authority="rfc3066">en</languageTerm>
<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
</language>
<physicalDescription>
<internetMediaType>text/html</internetMediaType>
<extent unit="figures">4</extent>
<extent unit="references">26</extent>
<extent unit="words">3211</extent>
</physicalDescription>
<abstract lang="en">The crystallization behavior of a polyamide 6/organo‐modified montmorillonite (PA 6/OMMT) nanocomposite has been investigated by scanning chip calorimetry and wide‐angle X‐ray scattering, with emphasis placed on the evaluation of the effect of supercooling/cooling rate on the crystal/mesophase polymorphism of the PA 6 matrix. Presence of OMMT has negligible effect on the kinetics of formation of α‐crystals of PA 6 at low cooling rate while there is observed enhanced nucleation of γ‐mesophase on fast cooling. Furthermore, addition of OMMT leads to a distinct increase of the cooling rate required to completely vitrify the amorphous state. The performed experiments demonstrate that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at cooling conditions relevant in polymer processing.</abstract>
<abstract type="graphical" lang="en">It is demonstrated that the nucleating effect of OMMT in PA 6/OMMT nanocomposites is of particular importance at rapid cooling conditions. Presence of OMMT has negligible effect on the kinetics of α‐crystal formation in PA 6, while enhanced nucleation of γ‐mesophase is observed. The cooling rate required to completely vitrify the amorphous state is increased.</abstract>
<subject lang="en">
<genre>keywords</genre>
<topic>cooling rate</topic>
<topic>crystallizations</topic>
<topic>nanocomposites</topic>
<topic>polyamide 6</topic>
<topic>polymorphism</topic>
</subject>
<relatedItem type="host">
<titleInfo>
<title>Macromolecular Materials and Engineering</title>
</titleInfo>
<titleInfo type="abbreviated">
<title>Macromol. Mater. Eng.</title>
</titleInfo>
<genre type="journal">journal</genre>
<subject>
<genre>article-category</genre>
<topic>Communication</topic>
</subject>
<identifier type="ISSN">1438-7492</identifier>
<identifier type="eISSN">1439-2054</identifier>
<identifier type="DOI">10.1002/(ISSN)1439-2054</identifier>
<identifier type="PublisherID">MAME</identifier>
<part>
<date>2013</date>
<detail type="volume">
<caption>vol.</caption>
<number>298</number>
</detail>
<detail type="issue">
<caption>no.</caption>
<number>9</number>
</detail>
<extent unit="pages">
<start>938</start>
<end>943</end>
<total>6</total>
</extent>
</part>
</relatedItem>
<relatedItem type="preceding">
<titleInfo>
<title>Applied Macromolecular Chemistry and Physics</title>
</titleInfo>
<identifier type="ISSN">0003-3146</identifier>
<part>
<date point="end">1999</date>
<detail type="volume">
<caption>last vol.</caption>
<number>273</number>
</detail>
<detail type="issue">
<caption>last no.</caption>
<number>1</number>
</detail>
</part>
</relatedItem>
<identifier type="istex">2CAE4F3F6F214C2D912181892A3705445833746A</identifier>
<identifier type="DOI">10.1002/mame.201200253</identifier>
<identifier type="ArticleID">MAME201200253</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</accessCondition>
<recordInfo>
<recordContentSource>WILEY</recordContentSource>
<recordOrigin>WILEY‐VCH Verlag</recordOrigin>
</recordInfo>
</mods>
</metadata>
<enrichments>
<json:item>
<type>multicat</type>
<uri>https://api.istex.fr/document/2CAE4F3F6F214C2D912181892A3705445833746A/enrichments/multicat</uri>
</json:item>
<json:item>
<type>refBibs</type>
<uri>https://api.istex.fr/document/2CAE4F3F6F214C2D912181892A3705445833746A/enrichments/refBibs</uri>
</json:item>
</enrichments>
<serie></serie>
</istex>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/corpus/SimuPvV1/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 005C38 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    SimuPvV1
   |flux=    Istex
   |étape=   Corpus
   |type=    RBID
   |clé=     ISTEX:2CAE4F3F6F214C2D912181892A3705445833746A
   |texte=   Crystallization of a Polyamide 6/Montmorillonite Nanocomposite at Rapid Cooling
}}

Wicri

This area was generated with Dilib version V0.6.23.
Data generation: Thu Sep 15 17:34:16 2016. Site generation: Thu Sep 15 18:23:44 2016