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Reductive Carbonylation of o‐Nitrophenol with a Fe‐Pd Cluster‐Derived Heterogeneous Catalyst; CO Migration in [FePdPt(CO)4(Ph2PCH2PPh2)2]

Identifieur interne : 000577 ( France/Analysis ); précédent : 000576; suivant : 000578

Reductive Carbonylation of o‐Nitrophenol with a Fe‐Pd Cluster‐Derived Heterogeneous Catalyst; CO Migration in [FePdPt(CO)4(Ph2PCH2PPh2)2]

Auteurs : Braunstein [France] ; Kervennal [France] ; Jean-Luc Richert [France]

Source :

Abstract

High activity and selectivity is exhibited by the FePd cluster 1 on SiO2 in the reductive carbonylation of o‐nitrophenol to benzoxazol‐2‐one. A conventional catalyst prepared from iron oxalate and palladium acetate is far less effective. The catalyst prepared from 1 retains its activity even after repeated use.


Url:
DOI: 10.1002/anie.198507681


Affiliations:


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ISTEX:259B31B23804873FE3B49D60C8BD870E19F03209

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