Generalized linearization of kinetics of glucose isomerization to fructose by immobilized glucose isomerase.
Identifieur interne : 002597 ( Main/Exploration ); précédent : 002596; suivant : 002598Generalized linearization of kinetics of glucose isomerization to fructose by immobilized glucose isomerase.
Auteurs : E. Palazzi [Italie] ; A. ConvertiSource :
- Biotechnology and bioengineering [ 0006-3592 ] ; 1999.
English descriptors
- KwdEn :
- MESH :
- chemical , chemical synthesis : Fructose.
- chemical , metabolism : Aldose-Ketose Isomerases, Enzymes, Immobilized, Fructose, Glucose.
- Isomerism, Kinetics, Models, Chemical.
Abstract
The kinetic parameters of both glucose isomerization to fructose and immobilized glucose isomerase (GI) inactivation calculated under different conditions are compared and discussed. Utilizing these figures, the possibility of generalizing a linear model, previously proposed for the kinetics of glucose isomerization by immobilized glucose isomerase, is investigated, so as to apply them to whole ranges of temperature and concentrations of actual interest in industrial processes. The proposed model is a satisfactory approximation of the more involved Briggs-Haldane approach and substantially simplifies the problem of optimizing an industrial fixed-bed column for high-fructose corn syrup (HFCS) production.
PubMed: 10099606
Affiliations:
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Le document en format XML
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<affiliation wicri:level="1"><nlm:affiliation>Institute of Chemical and Process Engineering, University of Genoa, Via Opera Pia, 15, I-16145 Genoa, Italy.</nlm:affiliation>
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<author><name sortKey="Converti, A" sort="Converti, A" uniqKey="Converti A" first="A" last="Converti">A. Converti</name>
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<author><name sortKey="Palazzi, E" sort="Palazzi, E" uniqKey="Palazzi E" first="E" last="Palazzi">E. Palazzi</name>
<affiliation wicri:level="1"><nlm:affiliation>Institute of Chemical and Process Engineering, University of Genoa, Via Opera Pia, 15, I-16145 Genoa, Italy.</nlm:affiliation>
<country xml:lang="fr">Italie</country>
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<author><name sortKey="Converti, A" sort="Converti, A" uniqKey="Converti A" first="A" last="Converti">A. Converti</name>
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<series><title level="j">Biotechnology and bioengineering</title>
<idno type="ISSN">0006-3592</idno>
<imprint><date when="1999" type="published">1999</date>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aldose-Ketose Isomerases (metabolism)</term>
<term>Enzymes, Immobilized (metabolism)</term>
<term>Fructose (chemical synthesis)</term>
<term>Fructose (metabolism)</term>
<term>Glucose (metabolism)</term>
<term>Isomerism</term>
<term>Kinetics</term>
<term>Models, Chemical</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemical synthesis" xml:lang="en"><term>Fructose</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="metabolism" xml:lang="en"><term>Aldose-Ketose Isomerases</term>
<term>Enzymes, Immobilized</term>
<term>Fructose</term>
<term>Glucose</term>
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<keywords scheme="MESH" xml:lang="en"><term>Isomerism</term>
<term>Kinetics</term>
<term>Models, Chemical</term>
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<front><div type="abstract" xml:lang="en">The kinetic parameters of both glucose isomerization to fructose and immobilized glucose isomerase (GI) inactivation calculated under different conditions are compared and discussed. Utilizing these figures, the possibility of generalizing a linear model, previously proposed for the kinetics of glucose isomerization by immobilized glucose isomerase, is investigated, so as to apply them to whole ranges of temperature and concentrations of actual interest in industrial processes. The proposed model is a satisfactory approximation of the more involved Briggs-Haldane approach and substantially simplifies the problem of optimizing an industrial fixed-bed column for high-fructose corn syrup (HFCS) production.</div>
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<affiliations><list><country><li>Italie</li>
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<country name="Italie"><noRegion><name sortKey="Palazzi, E" sort="Palazzi, E" uniqKey="Palazzi E" first="E" last="Palazzi">E. Palazzi</name>
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